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2 article(s) from Andraos, John

A proposed sustainability index for synthesis plans based on input provenance and output fate: application to academic and industrial synthesis plans for vanillin as a case study

John Andraos

Beilstein J. Org. Chem. 2020, 16, 2346–2362, doi:10.3762/bjoc.16.196

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Figure 1: Radial diamond diagrams illustrating the sustainability index (SI) computed based on F_VI, F_VO, F_VP,...

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Published 25 Sep 2020

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A new paradigm for designing ring construction strategies for green organic synthesis: implications for the discovery of multicomponent reactions to build molecules containing a single ring

John Andraos

Beilstein J. Org. Chem. 2016, 12, 2420–2442, doi:10.3762/bjoc.12.236

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Figure 1: Possible two-component couplings for various monocyclic rings frequently encountered in organic mol...

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Figure 2: Possible three-component couplings for various monocyclic rings frequently encountered in organic m...

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Figure 3: Possible four-component couplings for various monocyclic rings frequently encountered in organic mo...

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Figure 4: Permutations of two-component coupling patterns for synthesizing the cyclohexanone ring. Synthesis ...

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Figure 5: Permutations of two-component coupling patterns for synthesizing the cyclohexanone ring overlayed w...

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Scheme 1: Conjectured syntheses of cyclohexanone via [5 + 1] strategies.

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Scheme 2: Conjectured syntheses of cyclohexanone via [4 + 2] strategies.

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Scheme 3: Conjectured syntheses of cyclohexanone via [3 + 3] strategies.

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Figure 6: Permutations of three-component coupling patterns for synthesizing the cyclohexanone ring. Synthesi...

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Figure 7: Permutations of three-component coupling patterns for synthesizing the pyrazole ring via [2 + 2 + 1...

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Scheme 4: Literature method for constructing the pyrazole ring via the A4 [2 + 2 + 1] strategy.

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Scheme 5: Literature methods for constructing the pyrazole ring via the A5 [2 + 2 + 1] strategy.

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Scheme 6: Literature methods for constructing the pyrazole ring via the A1 [2 + 2 + 1] strategy.

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Scheme 7: Literature methods for constructing the pyrazole ring via the B4 [3 + 1 + 1] strategy.

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Figure 8: Intrinsic green performance of documented pyrazole syntheses according to [2 + 2 + 1] and [3 + 1 + ...

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Scheme 8: Conjectured reactions for constructing the pyrazole ring via the A2 and A3 [2 + 2 + 1] strategies.

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Scheme 9: Conjectured reactions for constructing the pyrazole ring via the B1, B2, B3, and B4 [3 + 1 + 1] str...

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Figure 9: Permutations of three-component coupling patterns for synthesizing the Biginelli ring adduct. Synth...

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Scheme 10: Reported syntheses of the Biginelli adduct via the traditional [3 + 2 + 1] mapping strategy.

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Scheme 11: Reported syntheses of the Biginelli adduct via new [3 + 2 + 1] mapping strategies.

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Scheme 12: Reported syntheses of the Biginelli adduct via a new [2 + 2 + 1 + 1] mapping strategy.

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Scheme 13: Conjectured syntheses of the Biginelli adduct via new [2 + 2 + 2] mapping strategies.

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Scheme 14: Conjectured syntheses of the Biginelli adduct via new [3 + 2 + 1] mapping strategies.

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Figure 10: Intrinsic green performance of documented Biginelli adduct syntheses according to [3 + 2 + 1] three...

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Figure 11: Intrinsic green performance of newly conjectured Biginelli adduct syntheses according to [4 + 1 + 1...

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Published 16 Nov 2016

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